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RARE EARTH
COORDINATION
CHEMISTRY
Rare Earth Coordination Chemistry: Fundamentals and Applications
Edited by Chunhui Huang
© 2010 John Wiley & Sons (Asia) Pte Ltd. ISBN: 978-0-470-82485-6
RARE EARTH
COORDINATION
CHEMISTRY
FUNDAMENTALS AND
APPLICATIONS
Editor
Chunhui Huang
Peking University, China
John Wiley & Sons (Asia) Pte Ltd
Copyright © 2010
John Wiley & Sons (Asia) Pte Ltd, 2 Clementi Loop, # 02-01,
Singapore 129809
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Library of Congress Cataloging-in-Publication Data
Rare earth coordination chemistry: fundamentals and applications / [edited by] Chunhui Huang.
p. cm.
Includes bibliographical references and index.
ISBN 978-0-470-82485-6 (cloth)
1. Rare earths. 2. Rare earth metal compounds. 3. Coordination compounds. I. Huang, Chunhui,
1933-QD172.R2R235 2010
546’.41—dc22
2010000191
ISBN 978-0-470-82485-6 (HB)
Typeset in 10/12pt Times by MPS Limited, AMacmillan Company.
Printed and bound in Singapore by Markono Print Media Pte Ltd, Singapore.
This book is printed on acid-free paper responsibly manufactured from sustainable forestry in which at least two
trees are planted for each one used for paper production.
Contents
Author Biographies
xiii
Foreword
xxi
Preface
xxiii
1
Introduction
1
Chunhui Huang and Zuqiang Bian
1.1 Electronic Configuration of LanthanideAtoms in the Ground State
1
1.2 Lanthanide Contraction
2
1.3 Specificity of the Photophysical Properties of Rare Earth Compounds
6
1.3.1 Spectral Terms
7
1.3.2 Selection Rules for Atomic Spectra
8
1.3.3 Lifetime
9
1.3.4 Absorption Spectra
10
1.3.5 The Emission Spectra of Rare Earth Compounds
11
1.4 Specificities of Rare Earth Coordination Chemistry
13
1.4.1 Valence State of Rare Earth Elements
14
1.4.2 Chemical Bonding of Rare Earth Elements
15
1.4.3 Coordination Numbers of Rare Earth Complexes
15
1.4.4 Tetrad Effect of Lanthanide Elements – Changing
Gradation Rules in Lanthanide Coordination Chemistry
21
1.5 Coordination Chemistry of Inorganic Compounds
25
1.5.1 Rare Earth Hydroxides
25
1.5.2 Rare Earth Halide and Perchlorate Compounds
26
1.5.3 Rare Earth Cyanide and Thiocyanate Compounds
27
1.5.4 Rare Earth Carbonate Compounds
28
1.5.5 Rare Earth Oxalate Compounds
30
1.5.6 Rare Earth Nitrate Compounds
31
1.5.7 Rare Earth Phosphate Compounds
32
1.5.8 Rare Earth Sulfate Compounds
34
1.5.9 Rare Earth Borate Compounds
36
1.6 Outlook
36
Acknowledgments
38
References
38
2
-Diketonate Lanthanide Complexes
41
β
Kezhi Wang
2.1
Introduction
41
2.2 Types of
β
-Diketones Used for Lanthanide Complexes
42
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