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Molecular Chemistry of
Sol-Gel Derived Nanomaterials
Molecular Chemistry of Sol-Gel Derived Nanomaterials
Robert Corriu and Nguyeˆn Trong Anh
© 2009 John Wiley & Sons, Ltd. ISBN: 978-0-470-72117-9
Molecular Chemistry of
Sol-Gel Derived Nanomaterials
Robert Corriu,
Universit´ Montpellier II, France
en Trong Anh,
´
cole Polytechnique, CNRS, France
^
Nguy
2009 John Wiley & Sons, Ltd
Originally published in French by
´
cole Polytechnique,
#
Robert Corriu and Nguyˆn Trong Anh, 2008
(978-2-730-21413-1).
Registered office
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#
Library of Congress Cataloging-in-Publication Data
Corriu, Robert.
Molecular chemistry of sol-gel derived nanomaterials/Robert Corriu, Nguyen Trong Anh.
p. cm.
‘‘Originally published in French by
´
cole Polytechnique.’’
Includes bibliographical references and index.
ISBN 978-0-470-72117-9
1. Colloids. 2. Nanofluids. 3. Nanochemistry. 4. Nanostructured
materials. I. Nguy
^
2008047063
A catalogue record for this book is available from the British Library.
Typeset in 10.5/13pt Sabon by Thomson Digital, Noida, India.
Printed and bound in Great Britain by TJ International Ltd, Padstow, Cornwall
ISBN 978-0-470-72117-9 (HB)
Copyright
en, Trong Anh, 1935- II. Title.
TA418.9.N35. C68313 2009
620.1
0
1–dc22
Contents
Preface
ix
About the Authors
xiii
1 Molecular Chemistry and Nanosciences
1
1.1 Introduction
1
1.2 Scope and Origin of Nanosciences: The ‘Top-Down’
and ‘Bottom-Up’ Approaches
2
1.3 Chemical Mutation: From an Exploratory
to a Creative Science
4
1.4 Carbon and Ceramic Fibers:
The Nanomaterial ‘Ancestors’
9
1.4.1 Carbon Fibers
9
1.4.2 SiC, Si
3
N
4
Ceramic Fibers
11
1.5 Conclusions
14
References
15
2 Nano-Objects
17
2.1 Introduction
17
2.2 Presentation of Nano-Objects
18
2.3 Synthesis of Nano-Objects
21
2.4 The Nano-Object: Entry into Nanosciences
22
2.4.1 Nano-Objects and the Exploration
of the Nanoworld
23
References
24
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